1-Butanol Separation from Aqueous Acetone-Butanol-Ethanol (ABE) Solutions by Freeze Concentration

نویسندگان

چکیده

The suspension freeze crystallization of aqueous 1-butanol solutions, synthetic acetone-butanol-ethanol (ABE) and ABE fermentation broth was studied as a novel concentration method that requires less energy than evaporation for water removal. equimolar solutions in total molality range 0–5.05 mol/kg(water) were proven to be ideal based on the freezing point depression obtained. An solution 8 wt % three different types (3:8:1:88 ABEW, 6:16:2:76 10:17:2:71 ABEW (wt %)) concentrated 80 min by subcooling from 0.24 1.15 °C. Freeze enabled separation generated mother liquor, which split into two liquid phases after ice separation, i.e., water-enriched phase 1-butanol-enriched phase. Ice yield values higher degrees initial content feed solutions. 1-Butanol yields separated liquors 9.85%, 59.46%, 22.46% 3:8:1:88 respectively, whereas two-stage broths resulted removal with maximum relative percentage 29.5%.

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ژورنال

عنوان ژورنال: Crystal Growth & Design

سال: 2023

ISSN: ['1528-7483', '1528-7505']

DOI: https://doi.org/10.1021/acs.cgd.2c01546